free energy
[热] 自由能
2026-03-21 08:14 浏览次数 18
[热] 自由能
1. the part of the energy of a portion of matter that may be changed without change of volume internal thermodynamic potential
2. available energy
lowest free nuclear energy最低自由核能
least free-energy最小自由能
Mean free adsorption energy平均吸附自由能
free-energy profile自由能剖面图
free surface energy自由表面能
free gibbs energy吉布斯自由能
free-energy fluctuation自由能起伏
free-energy minimization最小自由能法
And this is the Gibbs free energy per mole.
化学势是一摩尔物质的吉布斯自由能。
OK, now I have this derivative of the Gibbs free energy divided by the temperature.
现在要进行微分,对除以温度之后的吉布斯自由能。
So of course, the free energy in either case is just the sum of the number of moles of each times the chemical potential of each.
那么当然,任一种情况的自由能,就是各组分的分子数,乘以化学势再加和。
So we go back to writing what the Gibbs free energy is.
我们回到吉布斯自由能的表达式。
So there「s so much chemistry that takes place in liquid mixtures that it is really important to have a sense of what the free energy and chemical potential of each of the species is doing in there.
在液体混合物中发生,如此多的化学现象,以致了解每一种液体的,自由能和化学势,是怎样的非常重要。
So it becomes interesting, then, to figure out, how can we write the Helmholtz free energy in terms of the canonical partition function?
这就让我们开始思考,要怎么来表示亥姆霍兹自由能,用正则配分函数?
And then we can also write this in terms of the Gibbs free energy for the reaction.
然后我们可以用反应的,吉布斯自由能把它写出来。
Previous experiments and simulations, however, indicated that the free energy of hydration did not match this predicted linear trend.
然而,过去的研究和模拟表明,烷烃的水化自由能并不符合预计的线性变化趋势。
The Gibbs free energy per mole of a in the liquid phase.
液相中的化学势就是,液相中每摩尔a的吉布斯自由能。
So whatever their average free energy is, that」s going to add up and give us the total.
所有不论它们的平均自由能是什么,只要把它们加起来就会得到整体的值。
Could it be that having all this free energy lying around in fossil fuels offered us a dangerous dose of cultural steroids, the evolutionary equivalent of human growth hormone?
难道化石燃料里的自由能对于我们的文化进化过程,就相当于危险剂量的类固醇类激素对于人类的生长一样吗?
In other words, there「s a free energy per molecule.
换句话说,存在每个分子的自由能。
So we need to know the free energy of each one of the species.
所以我们需要知道,就是各种物质的自由能。
So we can replace this with the change in Gibbs free energy from going from gas to liquid.
所以这一项我们可以替代它,用从气相到液相变化的吉布斯自由能。
Let」s see that a little more explicitly by just calculating out the free energy change of mixing.
让我们通过计算出,混合物中自由能的变化,使问题更加清楚。
Whereas under these conditions, these quantities, if you look at free energy change, for example at constant temperature and pressure, H you can still calculate H.
但是,在这些条件下,这些物理量,如果我们考察自由能的变化,例如在恒定的温度和压强下,我们仍然可以计算。
What this is telling us is that we just have a chemical potential, of Helmholtz free energy per molecule.
这告诉我们的是,我们只有化学势,每个分子的亥姆霍兹自由能。
So this means that they were taking the derivatives of the Gibbs free energy with respect to one of its variables is something that we should know.
这意味着,当我们对吉布斯自由能求它的变量,的偏导数的时候,我们会得到我们以前学过的东西。
And this is just the Gibbs free energy per mole of a in the gas phase.
气相中的化学势,就是气相中每摩尔a的吉布斯自由能。
The key to this efficiency is the free energy arriving by stochastic resonance.
装置效率的关键在于随机共振所能带来的免费能量。
We learned that the pressure dependence of the Gibbs free energy gives you the pressure dependence for the chemical potential.
我们还知道吉布斯自由能,对压强的依赖关系决定了,化学势对压强的依赖关系。